The thermal decomposition of carbohydrates. Industrial Engineering Chemical Research 38, Tetrahedron Letters 47, Synthesis of and NMR studies on the four diastereomeric 1-deoxy-D-ketohexoses. Carrera 5, No 59A, Edif. General , Carbohydrate Research 2 ,
The Lobry de Bruyn-Alberda van Ekenstein transformation and related reactions. A convenient access to 1,5-anhydroketoses. Journal Agriculture Food Chemistry 54, Isomerization of glucose into fructose in the presence of cation-exchanged zeolites and hydrotalcites. Tetrahedron Letters 47, Isomerisation of aldoses in pyridine in the presence of aluminium oxide.
Aldose; ketose; efficiency; interconversion; selectivity.
Of the methods analyzed, the most promising are the ones that use ionic liquids due to the fact that they are fast and largely selective, but developing the technology that uses this type of liquids for the interconversion of a particular aldose-ketose pair is a challenge for research in the coming years. A Window of Opportunities.
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The thermal decomposition of carbohydrates. The objective of this review is to present the selectivity and efficiency of the alternatives reported in the literature for seerie interconversion of aldoses-ketoses, in order to evaluate the feasibility of its use in the food industry.
Advances in Carbohydrate Chemistry 10, Helvetica Chimica Acta 20, Glucose reactions with acid and base catalysts in hot compressed water at K.
Epimerization of glucose and mannose in the presence of nickel complexes of optically active ligands. Expedient conversion of D-glucose into 1,5-anhydro-Dfructose and into single stereogenic-center dihydropyranones, suitable six-carbon scaffolds for concise syntheses of the softcoral constituents – bissetone and palythazinel.
Detailed Reaction Pathway, Mechanisms, and Kinetics. Advanced Carbohydrate Chemistry and Biochemistry 39, A short note on the epimerization of aldoses. Industrial Engineering Chemical Research 38, H of and NMR studies on the four diastereomeric 1-deoxy-D-ketohexoses.
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Carbohydrate Research The Amadori rearrangement as key reaction for the synthesis of neoglycoconjugates. Protecting group strategies for carbohydrates. Journal of Carbohydrate Chemistry 16 4,5 Journal American Chemical Society Full text available only in PDF format. Applications of Ionic Liquids in Carbohydrate Chemistry: Physical Chemistry, Modification, and Process. Kinetics of formation and degradation of morpholinodeoxy-d-fructose, in Flavor Technology: Industrial Engineering Chemical Research 48 7 The Lobry de Bruyn-Alberda van Ekenstein transformation and related reactions.
Jounal American Chemical Society 5 Chemical Isomerization of glucose into fructose in the presence of cation-exchanged zeolites and hydrotalcites.
Advances in Carbohydrate Chemistry 11, Biomacromolecules 8 9 Analytical Chemistry 27 1 Carrera 5, No 59A, Edif.
German patentAgosto Organic Letters 3 6 Amadori ketoses with serje hydroxide and the Kiliani reaction on 1-deoxy ketoses: The reactivity of cyclic acetals of aldoses and aldosides. Journal Agriculture Food Chemistry 54, Journal of colloid interface science General Analytical Chemistry 78, Advances in Carbohydrate Chemistry 13, Advanced Carbohydrate Chemistry and Biochemistry 47, Alkali Metal Complexes of Carbohydrates.
Tetrahedron Letters 47, However, while the technology that uses enzymes is mature, non-enzymatic technologies are not fully developed. Advances in Carbohydrate Chemistry 20, Comparative study of C 2 epimerization of D-glucose and D-mannose catalyzed by water soluble organometallic complexes with nitrogen ligands, Journal of Molecular Catalysis A: Epimerization and fragmentation of glucose by quaternary ammonium base type anion exchange resins, Farben Industrie, A.
The enzymatic and non-enzymatic isomerization of aldoses to ketoses is a widely studied process. Isomerization of D-glucosa to D-fructosa over metallosilicate solid bases. Carbohydrate Research 12 Tetrahedron Letters 21 15, Substrate-dependent chemoselective aldose-aldose and aldose-ketose isomerizations of carbohydrates promoted by a combination of calcium ion and monoamines.
Towards improving the utility of ketoses as organic raw materials.